Unlike FreeBSD, which lets you boot into single user mode from a startup menu, getting into Single User Mode in CentOS is a little more complicated. Here's how:
bash# reboot
ekernel) and press e again.<0/LogVol00
Enter <space> single after that, so you've got:
<0/LogVol00 single
That tells CentOS to boot at run-level 1 in single user mode. You can also type emergency instead of single, which does the same thing but doesn't start any of your init scripts.
b to boot.More info on single user mode and rescue mode is available from the CentOS docs.